Abstract The nano/microstructures with highly porous surface area have attracted tremendous attention, particularly the synthesis and tailoring of porous and hollow materials of high performance. In this paper, an easy method of cost-effective synthesis of hollow ceramic fiber membranes based on Hydroxyapatite, TiO2 and ZrO2 stabilized with Yttrium, is proposed by a single chemical route (polymeric precursor method) and a bio-template route (easy to degrade in thermal conditions). This article reports also the ZrTiO4 nanowires synthesis on a silicon (100) wafer in a single step deposition/thermal treatment. Template-directed membrane synthesis strategy was associated to the polymeric precursor route and spin-coating deposition technique. In this method, ZrTiO4 nanowire ceramic were synthesized by spin-coating thermal treatment technique using polycarbonate membrane as a template. According to the results, after heat-treatment by the template removal, the ZrTiO4 nanowire consists of uniformly deposited crystalline and porous nanoparticles that exhibited a higher surface area and a higher porosity. The polycrystalline nanowires were obtained at by thermal treatment with diameter in the range of 60-100 nm. Photoluminescence spectra were collected for fiber at room temperature. These characterizations demonstrate the morphology of structures formed, showing its hollow and porous conformation, suitable applications to advanced reinforced or device component material.